I will try to be even more clear than KK by adding some arrows to let you see the buttons!
Option 1: click on
PM button

to contact that user directly (indicated by the
red arrow in picture 1).
Option 2: click on the "
0 new messages" link (indicated by the
blue arrow in picture 1) next to "
user control panel" to open your inbox and then (see second picture) click on
NEWPM button (indicated by the
green arrow in picture 2) to create a new message.
message1.jpg
message2.jpg